Pursat Province is bordered with Kampong Speu and Kampong Thom to the East, Battambang to the West, Koh Kong, and Thailand to the South and Siem Reap to the North. The province is subdivided into 6 Districts and 1 City, which are further subdivided into 42 Communes (Khum), 7 Sangkats and 511 Villages (Phum).
| No | Code | Name in Khmer | Name in English | Commune | Sangkat | Village |
| 01 | 1501 |
បាកាន |
Bakan |
9 | 0 | 131 |
| 02 | 1502 |
កណ្ដៀង |
Kandieng |
9 | 0 | 110 |
| 03 | 1503 |
ក្រគរ |
Krakor |
11 | 0 | 105 |
| 04 | 1504 |
ភ្នំក្រវ៉ាញ |
Phnum Kravanh |
6 | 0 | 44 |
| 05 | 1505 |
ក្រុងពោធិ៍សាត់ |
Pursat City |
0 | 7 | 66 |
| 06 | 1506 |
វាលវែង |
Veal Veaeng |
5 | 0 | 20 |
| 07 | 1507 |
តាលោសែនជ័យ |
Ta Lou Senchey |
2 | 0 | 35 |